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Studies in sesquiterpenes-XX. Acetoxymethylation of longifolene

Nayak, Ramdas U and Santhanakrishnan, TS and Dev, Sukh (1963) Studies in sesquiterpenes-XX. Acetoxymethylation of longifolene. In: Tetrahedron, 19 (12). pp. 2281-2292.

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Official URL: http://dx.doi.org/10.1016/0040-4020(63)85044-9


Longifolene in Prins reaction with formaldehyde yielded the expected ω-acetoxymethyl longifolene, which was transformed into a number of interesting derivatives. Configuration of the Prins product has been arrived at by NMR measurements. The UV absorption of these derivatives show a considerable bathochromic shift with respect to those in the camphene series and this could be attributed to the slight twisting of the ethylenic linkage in longifolene and its derivatives.

Item Type: Journal Article
Publication: Tetrahedron
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 25 May 2010 06:38
Last Modified: 19 Sep 2010 06:07
URI: http://eprints.iisc.ac.in/id/eprint/28124

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