Nayak, Ramdas U and Santhanakrishnan, TS and Dev, Sukh (1963) Studies in sesquiterpenes-XX. Acetoxymethylation of longifolene. In: Tetrahedron, 19 (12). pp. 2281-2292.
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Official URL: http://dx.doi.org/10.1016/0040-4020(63)85044-9
Abstract
Longifolene in Prins reaction with formaldehyde yielded the expected ω-acetoxymethyl longifolene, which was transformed into a number of interesting derivatives. Configuration of the Prins product has been arrived at by NMR measurements. The UV absorption of these derivatives show a considerable bathochromic shift with respect to those in the camphene series and this could be attributed to the slight twisting of the ethylenic linkage in longifolene and its derivatives.
| Item Type: | Journal Article |
|---|---|
| Publication: | Tetrahedron |
| Publisher: | Elsevier Science |
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 25 May 2010 06:38 |
| Last Modified: | 19 Sep 2010 06:07 |
| URI: | http://eprints.iisc.ac.in/id/eprint/28124 |
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