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Raman spectrum of ethyl chloroacetate

Neelakantan, P (1964) Raman spectrum of ethyl chloroacetate. In: Proceedings of the Indian Academy of Sciences - Section A, 59 (6). pp. 385-389.

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The Raman spectrum of ethyl chloroacetate has been studied at 13° C., 28° C. and 78° C. The carbonyl frequency was found to be split up into two due to the presence of rotational isomers. The higher frequency line due to thecis isomer was found to decrease in intensity with temperature. It appears that the gauche isomer will predominate in the vapour state. Altogether thirty-eight Raman lines have been recorded. Reasonable assignments for the observed Raman lines were made in comparison with ethyl acetate spectrum.

Item Type: Journal Article
Publication: Proceedings of the Indian Academy of Sciences - Section A
Publisher: Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 03 Jun 2010 05:46
Last Modified: 19 Sep 2010 06:07
URI: http://eprints.iisc.ac.in/id/eprint/28008

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