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Dimethyl sulphoxide complexes of titanyl, zirconyl and thorium perchlorates

Krishnan, V and Patel, CC (1964) Dimethyl sulphoxide complexes of titanyl, zirconyl and thorium perchlorates. In: Journal of Inorganic and Nuclear Chemistry, 26 (12). pp. 2201-2206.

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Official URL: http://dx.doi.org/10.1016/0022-1902(64)80167-6


TiO·5DMSO(ClO4)2, ZrO·8DMSO(ClO4)2 and Th·12DMSO(ClO4)4 are prepared by reaction of the respective metal perchlorates with an excess of dimethyl sulphoxide. The last two complexes yield ZrO·6DMSO(ClO4)2 and Th·6DMSO(ClO4)4 on heating around 185°C, while the titanyl complex explodes at 190°C. The extra DMSO molecules in the zirconyl and thorium complexes seem to be held in the lattice. In the parent complexes, the co-ordinated DMSO molecules are bonded by oxygen to the metal atoms while in the DMSO complexes of zirconyl and thorium perchlorates, obtained by heating at 185°C, the bonding involves the sulphur, indicating a change in the bonding during the process of heating.

Item Type: Journal Article
Publication: Journal of Inorganic and Nuclear Chemistry
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 21 May 2010 05:35
Last Modified: 19 Sep 2010 06:07
URI: http://eprints.iisc.ac.in/id/eprint/27967

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