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Charge distribution, dipole moment and molecular structure of silyl compounds

Krishnamurthy, VN and Soundararajan, S (1965) Charge distribution, dipole moment and molecular structure of silyl compounds. In: Journal of Inorganic and Nuclear Chemistry, 27 (11). pp. 2341-2344.

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Official URL: http://dx.doi.org/10.1016/0022-1902(65)80125-7


The formal charge distribution and hence the electric moments of a number of halosilanes and their methyl derivatives have been calculated by the method of Image and Image . The difference between the observed and the calculated values in simple halosilanes is attributed to a change in the hybridization of the terminal halogen atom and in methyl halosilanes to the enhanced electron release of the methyl group towards silicon compared with carbon.

Item Type: Journal Article
Publication: Journal of Inorganic and Nuclear Chemistry
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 19 May 2010 06:14
Last Modified: 19 Sep 2010 06:07
URI: http://eprints.iisc.ac.in/id/eprint/27921

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