ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

A revised structure for the condensation product of 2-carbethoxycyclopentanone and ethyl cyanoacetate

Kasturi, TR and Srinivasan, A (1966) A revised structure for the condensation product of 2-carbethoxycyclopentanone and ethyl cyanoacetate. In: Tetrahedron, 22 (8). pp. 2575-2580.

[img] PDF
40.pdf - Published Version
Restricted to Registered users only

Download (416kB) | Request a copy
Official URL: http://dx.doi.org/10.1016/S0040-4020(01)99049-0

Abstract

The condensation product of 2-carbethoxycyclopentanone and ethyl cyanoacetate is ethyl 2-carbethoxycyclopentylidene cyanoacetate (IIa) and not the one described by Kon and Nanji. Similarly, 2-carbomethoxycyclopentanone and methyl cyanoacetate yield methyl 2-carbomethoxycyclopentylidene cyanoacetate (IIb). The by-products obtained in the first reaction are cyclopentylidene cyanoacetate (IV) and the enamine of 2-carbethoxycyclopentanone (VIa).

Item Type: Journal Article
Publication: Tetrahedron
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 14 May 2010 09:53
Last Modified: 19 Sep 2010 06:06
URI: http://eprints.iisc.ac.in/id/eprint/27848

Actions (login required)

View Item View Item