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Charge distribution in and dipole moments of some aliphatic alcohols

Krishnamurthy, SS and Soundararajan, S (1969) Charge distribution in and dipole moments of some aliphatic alcohols. In: Journal of Physical Chemistry, 73 (12). pp. 4036-4039.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100846a002


Using the treatment of Smith, et al.,1 charge distributions in several aliphatic alcohols and consequently their dipole moments have been evaluated. The dipole moments of trichloroethanol (2.04 D) and 1,3-dichloropropan-2-ol (2.11 D) have been measured in benzene solution at 35°. The results of evaluation and measurements are interpreted in terms of the occurrence of intramolecular interaction between the hydroxyl hydrogen and an acceptor atom X (halogen or oxygen) at the β-carbon atom.

Item Type: Journal Article
Publication: Journal of Physical Chemistry
Publisher: American Chemical Society
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 17 May 2010 07:12
Last Modified: 19 Sep 2010 06:05
URI: http://eprints.iisc.ac.in/id/eprint/27610

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