Highly regio-, chemo- and diastereoselective synthesis of oxa-bridged spirocycles: A novel observation of reverse selectivity

Muthusamy, Sengodagounder and Krishnamurthi, Janagiraman and Nethaji, Munirathnam (2005) Highly regio-, chemo- and diastereoselective synthesis of oxa-bridged spirocycles: A novel observation of reverse selectivity. In: Chemical Communications (30). pp. 3862-3864.

PDF highly.pdf - Published Version Restricted to Registered users only Download (286kB) | Request a copy

Abstract

The reverse regio- and diastereoselectivities are observed between the reactions involving 5- and 6-membered-ring cyclic carbonyl ylide dipoles with alpha-methylene ketones. A mild catalytic route to synthesize spirocyclic systems with high regio-, chemo- and diastereoselectivities is described.

Item Type:	Journal Article
Publication:	Chemical Communications
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	04 Jun 2010 06:52
Last Modified:	19 Sep 2010 06:05
URI:	http://eprints.iisc.ac.in/id/eprint/27609

Actions (login required)

View Item