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Enantioselective Total Synthesis of (+)-Eupenoxide and (+)-Phomoxide: Revision of Structures and Assignment of Absolute Configuration

Mehta, Goverdhan and Roy, Subhrangsu (2004) Enantioselective Total Synthesis of (+)-Eupenoxide and (+)-Phomoxide: Revision of Structures and Assignment of Absolute Configuration. In: Organic Letters, 6 (14). pp. 2389-2392.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol0492288

Abstract

Stereo- and enantioselective total syntheses of the novel, polyketide natural products ent-eupenoxide and ent phomoxide have been accomplished from the readily available Diels-Alder adduct of cyclopentadiene and p-benzoquinone. These synthetic studies necessitate the revision of the assigned stereostructures of the natural products and reveal their absolute configuration.

Item Type: Journal Article
Publication: Organic Letters
Publisher: American Chemical Society
Additional Information: Copyright for this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 25 Jan 2005
Last Modified: 19 Jan 2012 05:55
URI: http://eprints.iisc.ac.in/id/eprint/2661

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