Mukherjee, Anindita and Chakrabarty, Rajesh and Patra, Goutam Kumar (2009) Novel 3-dimensional sixfold interpenetrating diamondoid networks of copper(I) coordination polymers of polypyridyl ligands - Syntheses,characterization and crystal structures. In: Inorganic Chemistry Communications, 12 (12). pp. 1227-1230.
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Abstract
Two new coordination polymers [Cu(L-1)(2)](n)(ClO4)(n)center dot 2nH(2)O (1), [Cu(L-2)(2)](n)(ClO4)(n)center dot 2nH(2)O (2) of polydentate imine/pyridyl ligands, L-1 and L-2 with Cu(I) ion have been synthesized and characterized by single crystal X-ray diffraction studies, elemental analyses, IR' UV-vis and NMR spectroscopy. They represent 3-dimensional, sixfold interpenetrating diamondoid network structures having large pores of dimension, 35 x 21 angstrom(2) in 1 and 38 x 19 angstrom(2) in 2, respectively.
Item Type: | Journal Article |
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Publication: | Inorganic Chemistry Communications |
Publisher: | Elsevier Science |
Additional Information: | Copyright of this article belongs to Elsevier Science. |
Keywords: | N-donor ligands;Coordination polymer;3D polymer; Copper(I) complexes;Sixfold interpenetration;Diamondoid networks; Crystal structures. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 08 Jan 2010 12:26 |
Last Modified: | 19 Sep 2010 05:54 |
URI: | http://eprints.iisc.ac.in/id/eprint/25313 |
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