In situ cryocrystallization of low melting chloro and bromo substituted anilines

Nayak, Susanta K and Prathapa, SJ and Row, Guru TN (2009) In situ cryocrystallization of low melting chloro and bromo substituted anilines. In: Journal of Molecular Structure, 935 (1-3). pp. 156-160. (Submitted)

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Abstract

In situ cryocrystallographic Studies of chloro and bromo substituted anilines have been performed to evaluate the role of halogen...halogen interactions and the subsequent formation of supramolecular assemblies in the solid state. Ortho Cl/Br substituted anilines are isostructural and belong to the trigonal P3(1) space group. Halogen...halogen intermolecular contacts along with stronger N-H center dot center dot center dot N hydrogen bonds generate helical motifs along the crystallographic c-axis. (C) 2009 Elsevier B.V. All rights reserved.

Item Type:	Journal Article
Publication:	Journal of Molecular Structure
Publisher:	Elsevier Science
Additional Information:	Copyright for this article belongs to Elsevier Science.
Keywords:	In situ cryocrystallography; Low melting liquids; Ortho halogenated anilines; Crystal structure
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	09 Dec 2009 09:47
Last Modified:	19 Sep 2010 05:52
URI:	http://eprints.iisc.ac.in/id/eprint/24821

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