Adsorption isotherms-microscopic modelling

Rangarajan, SK (1977) Adsorption isotherms-microscopic modelling. In: Journal of Electroanalytical Chemistry, 82 (1-2). pp. 93-132.

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Abstract

The phenomenon of adsorption is governed by the various interactions among the constituents of the interface and the forms of adsorption isotherms hold the clue to the nature of the se in teractions. An understanding of this phenomenon may be said to be complete only when the parameters occurring in such expres - sions for isotherms are interpretable in terms of molecular/electronic interactions.This objective viz. expressing the composition of the isotherm parameters through a microscopic modelling is by no means a simple one. Such a task is particularly made difficult in the case of charged interfaces where idealisation is difficult to make and, when made, not so easy to justify.

Item Type:	Journal Article
Publication:	Journal of Electroanalytical Chemistry
Publisher:	Elsevier Science
Additional Information:	copyright of this article belongs to Elsevier Science
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	19 Oct 2009 05:52
Last Modified:	19 Sep 2010 05:49
URI:	http://eprints.iisc.ac.in/id/eprint/24339

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