Studies of phosphazenes. Part I. Reactions of octachlorocyclotetraphosphazatetraene with ethylamine

Krishnamurthy, SS and Shaw, Robert A and Woods, Michael and Keat, Rodney and Sau, Arjun Chandra and Murthy, AR Vasudeva (1976) Studies of phosphazenes. Part I. Reactions of octachlorocyclotetraphosphazatetraene with ethylamine. In: Dalton Transactions, 14 . pp. 1405-1410.

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Abstract

The reaction of octachlorocyclotetraphosphazatetraene, N4P4Cl8, with ethylamine has been investigated. Seven derivatives, N4P4Cl8–n(NHEt)n[n= 1, 2 (two isomers), 3, 4 (two isomers), and 8] have been isolated and their structures established by 1H and 31P n.m.r. spectroscopy. A non-geminal chlorine atom replacement scheme is observed. Attempts to prepare penta- or hexa-ethylamino derivatives were unsuccessful: only sticky, non-crystalline resins were obtained from 1 : 10 or 1 : 12 reactions. The preparation and n.m.r. spectroscopic data of mixed ethylamino(methoxy)-derivatives. N4P4(NHEt)–8-n(OMe)n[n= 6, 4 (two isomers)], and an ethylamino-(dimethylamino)-derivative, N4P4(NHEt)2(NMe2)6, are generally consistent with the proposed structures. The reaction pattern is discussed.

Item Type:	Journal Article
Publication:	Dalton Transactions
Publisher:	RSC Publishing
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	09 Dec 2009 10:11
Last Modified:	19 Sep 2010 05:49
URI:	http://eprints.iisc.ac.in/id/eprint/24322

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