Chaturvedi, Jyotsna and Bhattacharya, Subrato and Nethaji, M (2009) Synthesis of a one-dimensional coordination polymer containing pendant hydrosulfide groups. In: Dalton Transacations (38). pp. 8018-8024.
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Abstract
In view of the recent interest in compounds containing M-SH units, an organotin hydrosulfide compound, Me2Sn(SH)(O2CMe) (1) was prepared by controlled hydrolysis of the diorganotin thioacetate. Under similar mild hydrolytic conditions the corresponding benzoate could not be isolated. Instead, the thiobenzoate complex, Me2Sn(SOCPh)(2) (3) was obtained in excellent yields indicating that there was no hydrolysis. Both 1 and 3 were characterized by X-ray crystallography. Some properties of the polymeric compound 1, such as spectral, electrical conductivity and NLO response were also studied. The reactivity and properties were explained using density functional calculations.
Item Type: | Journal Article |
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Publication: | Dalton Transacations |
Publisher: | Royal Society of Chemistry |
Additional Information: | Copyright of this article belongs to Royal Society of Chemistry, 2009. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 17 Dec 2009 11:56 |
Last Modified: | 19 Sep 2010 05:49 |
URI: | http://eprints.iisc.ac.in/id/eprint/24229 |
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