ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Synthesis of a one-dimensional coordination polymer containing pendant hydrosulfide groups

Chaturvedi, Jyotsna and Bhattacharya, Subrato and Nethaji, M (2009) Synthesis of a one-dimensional coordination polymer containing pendant hydrosulfide groups. In: Dalton Transacations (38). pp. 8018-8024.

[img] PDF
fulltext.pdf - Published Version
Restricted to Registered users only

Download (352kB) | Request a copy
Official URL: http://www.rsc.org/publishing/journals/DT/article....


In view of the recent interest in compounds containing M-SH units, an organotin hydrosulfide compound, Me2Sn(SH)(O2CMe) (1) was prepared by controlled hydrolysis of the diorganotin thioacetate. Under similar mild hydrolytic conditions the corresponding benzoate could not be isolated. Instead, the thiobenzoate complex, Me2Sn(SOCPh)(2) (3) was obtained in excellent yields indicating that there was no hydrolysis. Both 1 and 3 were characterized by X-ray crystallography. Some properties of the polymeric compound 1, such as spectral, electrical conductivity and NLO response were also studied. The reactivity and properties were explained using density functional calculations.

Item Type: Journal Article
Publication: Dalton Transacations
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry, 2009.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 17 Dec 2009 11:56
Last Modified: 19 Sep 2010 05:49
URI: http://eprints.iisc.ac.in/id/eprint/24229

Actions (login required)

View Item View Item