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Thermal decomposition of methylammonium perchlorate

Nambiar, PR and Verneker, VR Pai and Jain, SR (1975) Thermal decomposition of methylammonium perchlorate. In: Journal of Thermal Analysis, 7 (3). 587 -592.

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The thermal decomposition of methylammonium perchlorate (MAP) has been studied under isothermal and non-isothermal conditions. Differential thermal analysis of MAP showed, in addition to the exotherm due to decomposition, another exotherm at 408° which was observed for the first time. Chemical analysis and the infrared spectrum of the residue left behind after the decomposition proved it to contain NH4ClO4. The results have been explained on the basis of a methyl group transfer in addition to proton transfer in the decomposition process.

Item Type: Journal Article
Publication: Journal of Thermal Analysis
Publisher: John Wiley & Sons Ltd
Additional Information: Copyright of this article belongs to John Wiley & Sons Ltd.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 22 Jan 2010 06:40
Last Modified: 12 Nov 2018 15:44
URI: http://eprints.iisc.ac.in/id/eprint/24110

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