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Structural assignment of monothiocarbonohydrazones by 1H NMR spectroscopy

Rajendran, G and Jain, Sampat R (1984) Structural assignment of monothiocarbonohydrazones by 1H NMR spectroscopy. In: Organic Magnetic Resonance, 22 (1). pp. 6-10.

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Analysis of the 1H NMR spectra of several monothiocarbonohydrazones, some of them synthesized for the first time, shows that they exist as two structural isomers. Whereas, in general, the derivatives of aromatic aldehydes conform to a linear structure, the aliphatic carbonyl derivatives conform to heterocyclic or linear structures, depending on the size of the substituent groups. This dual behaviour is explained in terms of extended conjugation and steric hindrance.

Item Type: Journal Article
Publication: Organic Magnetic Resonance
Publisher: Wiley Interscience
Additional Information: Copyright for this article belongs to Wiley Interscience.
Department/Centre: Division of Mechanical Sciences > Aerospace Engineering(Formerly Aeronautical Engineering)
Date Deposited: 28 Jan 2010 05:05
Last Modified: 19 Sep 2010 05:48
URI: http://eprints.iisc.ac.in/id/eprint/24067

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