Investigations on the preparation, oxidation and reduction reactions of thiophosphoryl fluoride

Padma, DK and Vijayalakshmi, SK and Vasudevamurthy, AR (1976) Investigations on the preparation, oxidation and reduction reactions of thiophosphoryl fluoride. In: Journal of Fluorine Chemistry, 8 (6). pp. 461-465.

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Abstract

Pure thiophosphoryl fluoride has been prepared by the fluorination of thiophosphoryl chloride by sodium fluoride in acetonitrile medium. Oxidation of this phosphoryl fluoride by acidified chloramine-T ruptures the phosphorus-sulphur bond and oxidises the sulphur present to the hexavalent state. Anhydrous hydrogen iodide reduces the sulphur to hydrogen sulphide and phosphorus to the trivalent state.

Item Type:	Journal Article
Publication:	Journal of Fluorine Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	11 Dec 2009 07:33
Last Modified:	19 Sep 2010 05:48
URI:	http://eprints.iisc.ac.in/id/eprint/23965

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