Padma, DK and Vijayalakshmi, SK and Vasudevamurthy, AR (1976) Investigations on the preparation, oxidation and reduction reactions of thiophosphoryl fluoride. In: Journal of Fluorine Chemistry, 8 (6). pp. 461-465.
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Abstract
Pure thiophosphoryl fluoride has been prepared by the fluorination of thiophosphoryl chloride by sodium fluoride in acetonitrile medium. Oxidation of this phosphoryl fluoride by acidified chloramine-T ruptures the phosphorus-sulphur bond and oxidises the sulphur present to the hexavalent state. Anhydrous hydrogen iodide reduces the sulphur to hydrogen sulphide and phosphorus to the trivalent state.
Item Type: | Journal Article |
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Publication: | Journal of Fluorine Chemistry |
Publisher: | Elsevier Science |
Additional Information: | Copyright of this article belongs to Elsevier Science. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 11 Dec 2009 07:33 |
Last Modified: | 19 Sep 2010 05:48 |
URI: | http://eprints.iisc.ac.in/id/eprint/23965 |
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