Thermal Decomposition of hydrazinium monoperchlorate in the solid state

Verneker, VR Pai and Sharma, A Nagaraja and Jain, SR (1976) Thermal Decomposition of hydrazinium monoperchlorate in the solid state. In: Thermochimica Acta, 17 (3). pp. 319-323.

PDF article2.pdf - Published Version Restricted to Registered users only Download (292kB) | Request a copy

Abstract

Hydrazinium monoperchlorate (HP-1) has been shown to decompose thermally in the solid state according to the chemical equation: 5N2H5CIO4 = 4NH4CIO4+1HCI+3N2+4H2O The activation energy for the evolution of HCl as determined mass spectrometrically is 8.05 kcal mol−1 in the temperature range of 80 to 120°C. The rate of decomposition is seen to be altered by doping HP-1 with small concentrations of SO2−4, Ca2+ and Al3+.

Item Type:	Journal Article
Publication:	Thermochimica Acta
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	11 Dec 2009 08:37
Last Modified:	19 Sep 2010 05:48
URI:	http://eprints.iisc.ac.in/id/eprint/23955

Actions (login required)

View Item