Crystal and molecular structure of 15-bromolongibornane-8,9-dione

Row, Tayur N Guru and Venkatesan, Kailasam (1976) Crystal and molecular structure of 15-bromolongibornane-8,9-dione. In: Perkin Transactions 2 (14). pp. 1716-1719.

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Abstract

The crystal and molecular structure of the title compound (1) has been determined by the heavy-atom method from 1038 observed three-dimensional photographic data. Crystals are orthorhombic, with a = 20.07 ± 0.02, b= 10.05 ± 0.02, c= 7.31 ± 0.01 Å, space group P212121, with Z= 4. The structure was refined by block diagonal leastsquares to R 0.099. The conformation of the norbornane moiety is discussed. The seven-membered ring portion of the molecule adopts an approximate chair conformation. The packing of the molecules in the crystal is mainly a consequence of van der Waals interactions.

Item Type:	Journal Article
Publication:	Perkin Transactions 2
Publisher:	RSC Publishing
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	11 Dec 2009 11:04
Last Modified:	19 Sep 2010 05:48
URI:	http://eprints.iisc.ac.in/id/eprint/23905

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