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Charge transfer in Chevrel phases

Yashonath, S and Hegde, MS and Sarode, PR and Rao, CNR and Umarji, AM and Subba Rao, GV (1981) Charge transfer in Chevrel phases. In: Solid State Communications, 37 (4). pp. 325-327.

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Abstract

Chemical shifts of Mo K-absorption edge and Mo core level binding energies in Ax Mo6 Ch8 (Ch = S, Se, Te) Chevrel phases show clear evidence for charge transfer from the A element to the Mo6 cluster. The chemical shifts vary linearly with the intercluster Mo-Mo distance as well as the rhombohedral parameter.

Item Type: Journal Article
Publication: Solid State Communications
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science Ltd
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 23 Dec 2009 07:18
Last Modified: 19 Sep 2010 05:47
URI: http://eprints.iisc.ac.in/id/eprint/23874

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