Charge transfer complexes of crown ethers with neutral organic gyama-acceptor, 2-dicyanoethylene 1,3-indane dione

Malini, R and Krishnan, V (1984) Charge transfer complexes of crown ethers with neutral organic gyama-acceptor, 2-dicyanoethylene 1,3-indane dione. In: Spectrochimica Acta Part A: Molecular Spectroscopy, 40 (3). pp. 323-328.

PDF 2.pdf - Published Version Restricted to Registered users only Download (275kB) | Request a copy

Abstract

The interaction of benzo-15-crown-5, dibenzo-18-crown-6 and dibenzo-24-crown-8 with 2-dicyanoethylene 1,3-indane dione in CH2Cl2 has been described in terms of the formation of 1 : 1 molecular complexes. The magnitude of association constants and thermodynamic parameters indicate cooperative interactions of oxygens with the acceptors. The 1H and 13C NMR spectra of the complexes show that gyama-gyama interactions are a major source of ground state stabilization in these complexes.

Item Type:	Journal Article
Publication:	Spectrochimica Acta Part A: Molecular Spectroscopy
Publisher:	Elsevier science
Additional Information:	Copyright for this article belongs to Elsevier science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	28 Jan 2010 05:26
Last Modified:	19 Sep 2010 05:47
URI:	http://eprints.iisc.ac.in/id/eprint/23782

Actions (login required)

View Item