Metal complexes of thiophene 2-thiocarboxamide. Proton and 13C NMR, IR and electronic spectral studies

Burman, Sudhir and Sathyanarayana, DN (1981) Metal complexes of thiophene 2-thiocarboxamide. Proton and 13C NMR, IR and electronic spectral studies. In: Journal of Inorganic and Nuclear Chemistry, 43 (6). pp. 1189-1192.

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Abstract

The complexes of thiophene 2-thiocarboxamide (TTCA) with some metal chlorides and bromides [M = Ni(II), Zn(II), Cd(II), Hg(II) and Cu(I)] are described. Elemental analyses, magnetic susceptibilities and conductance studies, electronic, IR, proton and 13C magnetic resonance spectra are reported. The results suggest exclusive coordination of TTCA through the thiocarbonyl sulfur. The influence of the thiophene ring on the donor properties of the thioamide are discussed.

Item Type:	Journal Article
Publication:	Journal of Inorganic and Nuclear Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	04 Jan 2010 11:31
Last Modified:	20 Mar 2014 04:33
URI:	http://eprints.iisc.ac.in/id/eprint/23630

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