Spirocyclic phosphazenes derived from the reaction of N3P3Cl6 and N4P4Cl8 with bifunctional reagents

Chandrasekhar, V and Krishnamurthy, SS and Vasudeva Murthy, AR and Shaw, Robert A and Woods, M (1981) Spirocyclic phosphazenes derived from the reaction of N3P3Cl6 and N4P4Cl8 with bifunctional reagents. In: Inorganic and Nuclear Chemistry Letters, 17 (5-6). pp. 181-185.

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Abstract

Four possible reaction paths may be envisaged when a chlorocyclophosphazene reacts with a bifunctional reagent (FIGURE). He have shown recently that 1,2-diaminoethane and ethanolamine react initially with N3P3CI 6 to give the spirocyclic derivatives, N3P3CI4(HNCH2CH2X) X = NH, 0 (I). Further reaction with these bifunctional reagents leads to the formation of non-crystalline resins [reaction (iii)] albeit two isomeric bls(spirocyclic)- ethanolamino derivatives were isolated in low yields (vSZ).

Item Type:	Journal Article
Publication:	Inorganic and Nuclear Chemistry Letters
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	04 Jan 2010 11:49
Last Modified:	19 Sep 2010 05:46
URI:	http://eprints.iisc.ac.in/id/eprint/23626

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