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Mixed ligand complexes in vinyl polymerization-II: [NN′-ethylenebis(salicylideneiminato)] (benzoylacetonato)cobalt(III) as an initiator

Thiagarajan, R and Nandi, US and Kalpagam, V (1982) Mixed ligand complexes in vinyl polymerization-II: [NN′-ethylenebis(salicylideneiminato)] (benzoylacetonato)cobalt(III) as an initiator. In: European Polymer Journal, 18 (3). 261 -264.

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The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN′-ethylenebis(salicylideneiminato)](benzoylacetonato)cobalt(III) has been studied in bulk and in benzene at 70° and 80°. The rate of polymerization is proportional to (concentration of the chelate)1/2 and the monomer exponent is close to 1.5. The activation energy and the kinetic and transfer constants are evaluated. A free radical mechanism has been proposed.

Item Type: Journal Article
Publication: European Polymer Journal
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Publisher.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 15 Dec 2009 07:18
Last Modified: 19 Sep 2010 05:45
URI: http://eprints.iisc.ac.in/id/eprint/23374

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