Spectroscopic and Coordination Behavior of α-Cyanothioacetamide

Ray, Arabinda and Sathyanarayana, DN (1973) Spectroscopic and Coordination Behavior of α-Cyanothioacetamide. In: Bulletin of the Chemical Society of Japan, 46 (7). pp. 1969-1972.

PDF 2.pdf - Published Version Restricted to Registered users only Download (666kB) | Request a copy

Abstract

α-Cyanothioacetamide (CTAM) complexes of cuprous chloride CuCl–2CTAM and cuprous bromide CuBr–2CTAM have been prepared. The infrared spectra of CTAM and its complexes, and the laser Raman spectrum of CTAM have been recorded. Assignment of the frequencies of the ligand has been made on the basis of a normal coordinate analysis using the Urey-Bradley force field. The copper (I) complexes are inferred to have thiocarbonyl sulfur and amide nitrogen bonded CTAM as evidenced from infrared and electronic spectra.

Item Type:	Journal Article
Publication:	Bulletin of the Chemical Society of Japan
Publisher:	Chemical Society of Japan
Additional Information:	Copy right of this article belongs to Chemical Society of Japan.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	06 Jan 2010 10:49
Last Modified:	19 Sep 2010 05:44
URI:	http://eprints.iisc.ac.in/id/eprint/23166

Actions (login required)

View Item