Sathyanarayana, DN and Burman, Sudhir (1982) Iron(II, III) complexes with N, N'-DI(2-)Pyridyl Thiourea. Moumlssbauer and other spectroscopic studies. In: Journal of Coordination Chemistry, 11 (4). pp. 219-223.
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Several iron(II, III) complexes of N, N'-di(2-)pyridyl thiourea have been synthesized. The preparation of the complexes from iron(III) salts proceeds through a reduction of iron(III) to iron(II) followed by a subsequent reoxidation. The Moumlssbauer, electronic and infrared spectra of these complexes have been measured. The results are concordant with the coordination of pyridine nitrogens and thiocarbonyl sulfur yielding polymeric complexes. A variable temperature NMR study of the free ligand shows that two conformation are accessible for it in solution at subambient temperatures.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of Coordination Chemistry |
| Publisher: | Taylor and Francis Group |
| Additional Information: | Copyright of this article belongs to Taylor and Francis Group |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 22 Dec 2009 09:05 |
| Last Modified: | 22 Dec 2009 09:05 |
| URI: | http://eprints.iisc.ac.in/id/eprint/23130 |
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