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Iron(II) and iron(III) complexes of 2,4-dithiobiuret

Burman, Sudhir and Sathyanarayana, Dixit N and Anagnostopoulos, Augostinos (1980) Iron(II) and iron(III) complexes of 2,4-dithiobiuret. In: Transition Metal Chemistry, 5 (1). pp. 52-55.

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Ferrous and ferric complexes of 2,4-dithiobiuret (Dtb) of the type Fe(Dtb)m Xn where m, n = 1-3, and X = CI–, Br–, I– and SO 4 2– , and a neutral Fe(Dtb-H)2 complex have been synthesized and characterised by elemental analyses, magnetic susceptibility, i.r., electronic and Mössbauer spectroscopic studies. From its i.r. spectrum Dtb was found to act as a S,S-coordinating bidentate chelate. The magnetic moment, electronic and Massbauer spectra are consistent with a low spin distorted octahedral structure for the ferric complexes and a high spin form for ferrous complexes.

Item Type: Journal Article
Publication: Transition Metal Chemistry
Publisher: Springer Netherlands
Additional Information: Copyright of this article belongs to Springer.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 03 Sep 2009 17:49
Last Modified: 19 Sep 2010 05:43
URI: http://eprints.iisc.ac.in/id/eprint/22723

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