Structure of (6S,13bR)-1,2,3,5,6,13b-hexahydro-6-isopropyl-8H-pyrrolo[1',2':1,2]pyrazino[3,4,-b]quinazoline-5,8-dione

Suguna, K and Ramakumar, S and Rajappa, S (1982) Structure of (6S,13bR)-1,2,3,5,6,13b-hexahydro-6-isopropyl-8H-pyrrolo[1',2':1,2]pyrazino[3,4,-b]quinazoline-5,8-dione. In: Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry, 38 (8). pp. 2304-2306.

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Abstract

C17H19N302, monoclinic, P21, a = 5.382 (1), b = 17.534(4), c = 8.198(1)/L ,8 = 100.46(1) °, Z= 2, d,, = 1.323, dc= 1.299 Mg m-3, F(000) = 316, /~(Cu .Ka) = 0.618 mm -1. R = 0.052 for 1284 significant reflections. The proline-containing cispeptide unit which forms part of a six-membered ring deviates from perfect planarity. The torsion angle about the peptide bond is 3.0 (5) ° and the peptide bond length is 1.313 (5)A. The conformation of the proline ring is Cs-Cf~-endo. The crystal structure is stabilized by C-H... O interactions.

Item Type:	Journal Article
Publication:	Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry
Publisher:	Wiley and sons
Additional Information:	Copyright of this article belongs to International Union of Crystallography.
Department/Centre:	Division of Physical & Mathematical Sciences > Physics
Date Deposited:	30 Dec 2009 07:25
Last Modified:	19 Sep 2010 05:42
URI:	http://eprints.iisc.ac.in/id/eprint/22598

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