Kumar, N and March, NH and Wasserman, A (1982) Critical-point Properties of Liquids and the Born-Green Theory. In: Physics and Chemistry of Liquids, 11 (3). pp. 271-275.
Full text not available from this repository. (Request a copy)Abstract
Recent work of Jones et al. giving the long-range behaviour of the pair correlation function is used to confirm that the critical ratio Pc/nckBTc = 1/2 in the Born-Green theory. This deviates from experimental results on simple insulating liquids by more than the predictions of the van der Waals equation of state. A brief discussion of conditions for thermodynamic consistency, which the Born-Green theory violates, is then given. Finally, the approach of the Ornstein-Zernike correlation function to its critical point behaviour is discussed within the Born-Green theory.
Item Type: | Journal Article |
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Publication: | Physics and Chemistry of Liquids |
Publisher: | Taylor and Francis Group |
Additional Information: | Copyright of this article belongs to Taylor and Francis Group. |
Department/Centre: | Division of Physical & Mathematical Sciences > Physics |
Date Deposited: | 25 Aug 2009 06:43 |
Last Modified: | 25 Aug 2009 06:43 |
URI: | http://eprints.iisc.ac.in/id/eprint/22499 |
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