Synthesis and characterization of a rare hemiacetalate bridged incomplete View the MathML source dicubane cluster

Mondal, Kartik Chandra and Sengupta, Oindrila and Mukherjee, Partha Sarathi (2009) Synthesis and characterization of a rare hemiacetalate bridged incomplete View the MathML source dicubane cluster. In: Inorganic Chemistry Communications, 12 (7). pp. 682-685.

PDF http___www.sciencedirect.com_science__ob=MImg&_imagekey=B6VM7-4WD1C5H-6-J&_cdi=6143&_user=512776&_orig=search&_coverDate=07%2F31%2F2009&_sk=999879992&view=c&wchp=dGLzVtb-zSkWz&md5=f4bfa156ecd2b44icle.pdf - Published Version Restricted to Registered users only Download (321kB) | Request a copy

Abstract

Reaction of 2-pyridinecarboxaldehyde [(Py)CHO] with Cu(NO3)2·2.5H2O in the presence of 4-aminopyridine and NaN3 in MeOH lead to an incomplete double-cubane [Cu4{PyCH(O)(OMe)}4(N3)4] (1) in 87% isolated yield, representing a rare type of metal cluster containing bridging hemiacetalate ligand [pyCH(O)(OMe)]−1 which was characterized by single crystal structure analysis and variable temperature magnetic behavior.

Item Type:	Journal Article
Publication:	Inorganic Chemistry Communications
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Keywords:	Antiferromagnetic;Crystal structure;Azide;Copper(II).
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	22 Dec 2009 09:18
Last Modified:	19 Sep 2010 05:42
URI:	http://eprints.iisc.ac.in/id/eprint/22454

Actions (login required)

View Item