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Thermal properties of 3BaO-3TiO(2)-B2O3 glasses

Vaish, Rahul and Varma, KBR (2009) Thermal properties of 3BaO-3TiO(2)-B2O3 glasses. In: Philosophical Magazine, 89 (19). pp. 1555-1564.

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Transparent glasses in the system 3BaO-3TiO2-B2O3 (BTBO) were fabricated via the conventional melt-quenching technique. The as-quenched samples were confirmed to be non-crystalline by differential thermal analysis (DTA). Thermal parameters were evaluated using non-isothermal DTA experiments. The Kauzmann temperature was found to be 759 K based on heating-rate-dependent glass transition and crystallization temperatures. A theoretical relation for the temperature-dependent viscosity is proposed for these glasses and glass-ceramics.

Item Type: Journal Article
Publication: Philosophical Magazine
Publisher: Taylor and Francis Group
Additional Information: Copyright of this article belongs to Taylor and Francis Group.
Keywords: calorimetry;crystallization;glass;glass ceramics;glass transition;kinetics.
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 22 Dec 2009 07:29
Last Modified: 19 Sep 2010 05:41
URI: http://eprints.iisc.ac.in/id/eprint/22438

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