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Reaction of thiophosphoryl fluoride with sulphur trioxide

Sampath Kumar, HP and Padma, DK and Vasudeva Murthy, AR (1984) Reaction of thiophosphoryl fluoride with sulphur trioxide. In: Journal of Fluorine Chemistry, 26 (1). pp. 117-123.

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Thiophosphoryl fluoride is observed to undergo a facile reaction with sulphur trioxide forming phosphoryl fluoride, sulphur dioxide and elemental sulphur in quantitative yields. In the presence of excess of sulphur trioxide, however, the elemental sulphur released combines with it to form sulphur sesquioxide which subsequently decomposes and gives off sulphur dioxide. Similar observations are made with oleum.

Item Type: Journal Article
Publication: Journal of Fluorine Chemistry
Publisher: Elsevier Science
Additional Information: Copyright for this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 30 Jan 2010 04:51
Last Modified: 19 Sep 2010 05:41
URI: http://eprints.iisc.ac.in/id/eprint/22418

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