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Some metal complexes with n-(2-pyridyl)thioacetamide and n-(2-pyridyl)thiobenzamide

Sudha, LV and Sathyanarayana, DN (1984) Some metal complexes with n-(2-pyridyl)thioacetamide and n-(2-pyridyl)thiobenzamide. In: Journal of Coordination Chemistry, 13 (3). 207 -214.

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The Cu(II). Zn(II) and Cd(II) chloride and bromide complexes of N-2(2-pyridyl)thioacetamide and N-(2-pyridyl)thiobenzamide have been prepared. The infrared and 1H and 13C NMR spectra of the complexes and the free ligands have been analysed to determine the coordination sites. It was concluded that N-(2-pyridyl)thioacetamide behaves as a bidentate ligand, chelating to the metal via pyridine nitrogen and thionamide sulfur atoms while the other ligand, N-(2-pyridyl)thiobenzamide coordinates to the metal atom as a unidentate through the pyridine nitrogen atom. Conformations of the free ligands are discussed.

Item Type: Journal Article
Publication: Journal of Coordination Chemistry
Publisher: Taylor and Francis Group
Additional Information: Copyright of this article belongs to Taylor and Francis Group.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 28 Jan 2010 11:30
Last Modified: 28 Jan 2010 11:30
URI: http://eprints.iisc.ac.in/id/eprint/22354

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