Inhibition of self-quenching in thioketones by micellar compartmentalization

Ramesh, V and Ramamurthy, V (1982) Inhibition of self-quenching in thioketones by micellar compartmentalization. In: Journal of Photochemistry, 20 (1). pp. 47-52.

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Abstract

The technique of micellar compartmentalization has been used to inhibit the diffusion-controlled self-quenching process in thioketones. By adjusting the ratio of the bulk concentration of the thioketone solute to the bulk concentration of micelles multiple occupancy of the micelles was avoided. Under these conditions enhanced phosphorescence intensity was observed in nitrogen-purged micellar solutions compared with that in acetonitrile solutions, indicating that the thioketone triple was indeed protected from deactivation by a ground statet

Item Type:	Journal Article
Publication:	Journal of Photochemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	25 Aug 2009 10:11
Last Modified:	19 Sep 2010 05:41
URI:	http://eprints.iisc.ac.in/id/eprint/22336

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