Investigations Of Glasses In The System Pbo-Pbf2

Rao, BG and Sundar, HGK and Rao, KJ (1984) Investigations Of Glasses In The System Pbo-Pbf2. In: Journal of the Chemical Society: Faraday Transaction 1, 80 . pp. 3491-3501.

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Abstract

Glass formation in the system PbO–PbF2 has been investigated. The structure of these glasses has been studied using X-ray diffraction. Densities, heat capacities, glass-transition and crystallization temperatures and Vicker's microhardnesses have been measured. D.c. conductivities of these glasses have also been measured as a function of temperature. A structural model has been developed which suggests the existence of [PbO2F4]-type units over the entire composition range. It is suggested that covalent linkages of the type—O—Pb—O— play a crucial role in determining the composition limits to glass formation. The structural model has been shown to be consistent with other physical properties of the glasses.

Item Type:	Journal Article
Publication:	Journal of the Chemical Society: Faraday Transaction 1
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	27 Aug 2009 04:10
Last Modified:	19 Sep 2010 05:41
URI:	http://eprints.iisc.ac.in/id/eprint/22250

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