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Aspects of tautomerism 9-solvolysis of normal and pseudo phthaloyl chlorides

Bhatt, Vivekananda M and Ashry, Shaker HEI and Somayaji, Vishwanatha (1980) Aspects of tautomerism 9-solvolysis of normal and pseudo phthaloyl chlorides. In: Journal of Chemical Sciences, 89, Nu (1). pp. 7-15.

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Abstract

Solvolysis of normal and pseudo phthaloyl chlorides in aqueous acetone and in aqueous dioxane has revealed that the former solvolyses about hundred-fold faster than the latter. Contrary to the accepted belief, there is no evidence for equilibrium between the normal and the pseudo forms of phthaloyl chloride, under a variety of conditions.

Item Type: Journal Article
Publication: Journal of Chemical Sciences
Publisher: Springer India, in co-publication with Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Springer in collaboration with Indian Academy of Sciences.
Keywords: Phthaloyl chloride isomerism;tautomerism;solvolysis.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 18 Aug 2009 04:37
Last Modified: 21 Feb 2019 10:43
URI: http://eprints.iisc.ac.in/id/eprint/22197

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