A comparative study of the photochemical hydrogen-abstraction reactions of a ketone and a thione

Sumathi, K and Chandra, AK (1988) A comparative study of the photochemical hydrogen-abstraction reactions of a ketone and a thione. In: Journal of Photochemistry and Photobiology A: Chemistry, 43 (3). pp. 313-327.

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Abstract

A perturbation treatment was developed for the comparative study of the abstraction of hydrogen from methane by formaldehyde and thioformaldehyde in their nπ* and ππ* states. Both in-plane and perpendicularplane reactions are considered. Results are qualitative but reveal clearly the prominent distinguishing features of these two photochemical processes in agreement with the experimental observations.

Item Type:	Journal Article
Publication:	Journal of Photochemistry and Photobiology A: Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	04 Aug 2009 03:17
Last Modified:	19 Sep 2010 05:39
URI:	http://eprints.iisc.ac.in/id/eprint/21996

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