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Complexes of Lanthanide Perchlorates with N-(2-Pyrimidyl)benzamide

Rajasekar, N and Soundararajan, S (1981) Complexes of Lanthanide Perchlorates with N-(2-Pyrimidyl)benzamide. In: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 11 (2). 99 - 107.

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New complexes of lanthanide perchlorates with N-(2-pyrimidyl)benzamide (BApymH) of the general formulae [Ln(BApymH)4](ClO4)3 (where Ln = La-Yb and Y) have been synthesised and characterised by chemical analysis, molar conductivity and physical methods such as infrared and electronic spectra in the visible region. Molar conductance and infrared data point to the ionic nature of the per-chlorate groups in the complexes. IR data unequivocally proves that the coordination of the ligand to the metal ion takes place in a bidentate fashion through the oxygen of the secondary amide and nitrogen of the pyrimidine ring. From a comparison of the visible electronic spectral shapes of the Nd3+ and Ho3+ complexes with those reported in the literature, an eight coordinate geometry around the metal ion has tentatively been assigned in all the complexes.

Item Type: Journal Article
Publication: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Publisher: Marcel Dekker Inc
Additional Information: Copyright of this article belongs to Marcel Dekker Inc
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 04 Aug 2009 03:26
Last Modified: 04 Aug 2009 03:26
URI: http://eprints.iisc.ac.in/id/eprint/21952

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