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A new formalism for representation of binary thermodynamic data

Hajra, JP (1980) A new formalism for representation of binary thermodynamic data. In: Metallurgical and Materials Transactions B, 11 (2). pp. 215-219.

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The applicability of a formalism involving an exponential function of composition x1 in interpreting the thermodynamic properties of alloys has been studied. The excess integral and partial molar free energies of mixing are expressed as: $$\begin{gathered} \Delta F^{xs} = a_o x_1 (1 - x_1 )e^{bx_1 } \hfill \\ RTln\gamma _1 = a_o (1 - x_1 )^2 (1 + bx_1 )e^{bx_1 } \hfill \\ RTln\gamma _2 = a_o x_1^2 (1 - b + bx_1 )e^{bx_1 } \hfill \\ \end{gathered} $$ The equations are used in interpreting experimental data for several relatively weakly interacting binary systems. For the purpose of comparison, activity coefficients obtained by the subregular model and Krupkowski’s formalism have also been computed. The present equations may be considered to be convenient in describing the thermodynamic behavior of metallic solutions.

Item Type: Journal Article
Publication: Metallurgical and Materials Transactions B
Publisher: Springer Boston
Additional Information: Copyright of this article belongs to Springer.
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited: 01 Feb 2010 10:26
Last Modified: 19 Sep 2010 05:39
URI: http://eprints.iisc.ac.in/id/eprint/21821

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