Coordinative interaction of morpholine with divalent metallo tetraphenyl porphyrins

Chandrashekar, TK and Krishnan, V (1981) Coordinative interaction of morpholine with divalent metallo tetraphenyl porphyrins. In: Journal of Inorganic and Nuclear Chemistry, 43 (12). pp. 3287-3290.

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Abstract

The formation of axially coordinated morpholine (morph) complexes of MTPP, (M = Co, Ni, Cu and Zn) has been studied. Morpholine coordinates through imino nitrogen to the metal ions with the retainment of equatorial conformation. The presence of spin-free, NiTPP (morph), (S = 1) and an equilibrium mixture of CoTPP and an oxygen adduct of CoTPP (morph) in solution have been observed.

Item Type:	Journal Article
Publication:	Journal of Inorganic and Nuclear Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	22 Jul 2009 06:38
Last Modified:	19 Sep 2010 05:38
URI:	http://eprints.iisc.ac.in/id/eprint/21695

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