ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

An elegant direct route for the preparation of pyridinium, ammonium and alkali metal hexafluorotitanates (IV)

Mohamed, Syed K and Padma, Doddaballapur K (1987) An elegant direct route for the preparation of pyridinium, ammonium and alkali metal hexafluorotitanates (IV). In: Journal of Fluorine Chemistry, 35 (2). pp. 411-414.

[img] PDF
3.pdf - Published Version
Restricted to Registered users only

Download (196kB) | Request a copy
Official URL: http://www.sciencedirect.com/science?_ob=MImg&_ima...

Abstract

Pyridinium hexafluorotitanate (IV) has been prepared by a one step procedure. Addition of titanium tetrachloride to pyridinium poly(hydrogen fluoride) yields nearly quantitative amounts of pyridinium hexafluorotitanate(IV). Making use of pyridinium hexafluorotitanate as precursor, ammonium and alkali metal (Na, K, Rb, and Cs) hexafluorotitanates have been prepared in good yields. These salts have been characterised by IR, N.M.R. (1H, 13C and 19F), X-ray powder diffraction data and chemical analysis.

Item Type: Journal Article
Publication: Journal of Fluorine Chemistry
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 15 Jul 2009 08:53
Last Modified: 19 Sep 2010 05:37
URI: http://eprints.iisc.ac.in/id/eprint/21507

Actions (login required)

View Item View Item