Metal Auger Intensity Ratios in Transition Metals and Their Compounds

Yashonath, S and Sen, P and Hedge, MS and Rao, CNR (1983) Metal Auger Intensity Ratios in Transition Metals and Their Compounds. In: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 79 (P5). 1229 -1236.

PDF F19837901229.pdf - Published Version Restricted to Registered users only Download (510kB) | Request a copy

Abstract

Metal Auger intensity ratios of the type Z(CVV)/I(CC'V) and Z(CVV)/Z(CC'C"), where C, C' and C" denote core levels and V stands for a valence level, are shown to increase progressively with the number of valence electrons in the metal in the case of second-row transition metals and their oxides. Metal Auger intensity ratios in chalcogenides of transition metals can be correlated by taking the effective atomic charge on the metal into consideration. The possible use of metal Auger intensity ratios in the study of surface oxidation of second-row transition metals is illustrated in the case of zirconium.

Item Type:	Journal Article
Publication:	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	02 Feb 2010 10:46
Last Modified:	19 Sep 2010 05:37
URI:	http://eprints.iisc.ac.in/id/eprint/21434

Actions (login required)

View Item