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Unusual Structural Isomerization Of Monopropiophenone Thiocarbonohydrazone

Rajendran, G and Jain, SR (1984) Unusual Structural Isomerization Of Monopropiophenone Thiocarbonohydrazone. In: Organic Magnetic Resonance, 22 (9). pp. 550-551.

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Monopropiophenone thiocarbonohydrazone has been isolated in both linear and cyclic isomeric forms. Each form has been shown to isomerize and exist in equilibrium with the other in DMSO-d6 solution by 1H and 13C NMR spectroscopy. The kinetics of this transformation show attainment of equilibrium in approximately 6 h, with a linear to cyclic configuration ratio of 40:60.

Item Type: Journal Article
Publication: Organic Magnetic Resonance
Publisher: John Wiley & Sons
Additional Information: Copyright for this article belongs to John Wiley & Sons.
Department/Centre: Division of Mechanical Sciences > Aerospace Engineering(Formerly Aeronautical Engineering)
Date Deposited: 08 Feb 2010 10:51
Last Modified: 19 Sep 2010 05:34
URI: http://eprints.iisc.ac.in/id/eprint/20655

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