Unusual Structural Isomerization Of Monopropiophenone Thiocarbonohydrazone

Rajendran, G and Jain, SR (1984) Unusual Structural Isomerization Of Monopropiophenone Thiocarbonohydrazone. In: Organic Magnetic Resonance, 22 (9). pp. 550-551.

PDF fulltext.pdf3.pdf - Published Version Restricted to Registered users only Download (177kB) | Request a copy

Abstract

Monopropiophenone thiocarbonohydrazone has been isolated in both linear and cyclic isomeric forms. Each form has been shown to isomerize and exist in equilibrium with the other in DMSO-d6 solution by 1H and 13C NMR spectroscopy. The kinetics of this transformation show attainment of equilibrium in approximately 6 h, with a linear to cyclic configuration ratio of 40:60.

Item Type:	Journal Article
Publication:	Organic Magnetic Resonance
Publisher:	John Wiley & Sons
Additional Information:	Copyright for this article belongs to John Wiley & Sons.
Department/Centre:	Division of Mechanical Sciences > Aerospace Engineering(Formerly Aeronautical Engineering)
Date Deposited:	08 Feb 2010 10:51
Last Modified:	19 Sep 2010 05:34
URI:	http://eprints.iisc.ac.in/id/eprint/20655

Actions (login required)

View Item