Low temperature fluorination of sulphur compounds with elemental fluorine

Padma, DK and Bhat, V Subrahmanya and Murthy, AR Vasudeva (1982) Low temperature fluorination of sulphur compounds with elemental fluorine. In: Journal of Fluorine Chemistry, 21 (1). p. 40.

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Abstract

Low temperature fluorination technique is adopted for fluorination of the following sulphur compounds in freon-11 medium (1) Sulphur dioxide (2) Thionyl chloride (3) Sulphuryl chloride (4) Tetrasulphur tetra nitride and (5) Sulphur bromide. All the compounds undergo oxidative fluorination to give rise to sulphur-fluorine compounds except sulphuryl chloride which resists fluorination. Sulphuryl chloride thus behaves as a good solvent medium for fluorination of other reactive compounds like elemental sulphur. Details of the experimental procedures adopted and the identification of the products will be presented.

Item Type:	Journal Article
Publication:	Journal of Fluorine Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	04 Sep 2009 04:51
Last Modified:	19 Sep 2010 05:32
URI:	http://eprints.iisc.ac.in/id/eprint/20393

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