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Thermal Analysis of Polypropylene Hydroperoxide

Kishore, K (1983) Thermal Analysis of Polypropylene Hydroperoxide. In: Journa of Macromolecular Science, Part A, 19 (6). 937 -942.

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Official URL: http://www.informaworld.com/smpp/469341295-5681676...


Studies on the low temperature oxidation of polyolefins have been the subject matter of several investigations because of interest in understanding the aging and weathering of polymers. One of the key steps in such an oxtdatton is the formation of hydroperoxide. Estimation of the hydroperoxide in oxidized samples, which is conventionally done by iodometric titrations, is quite important to gain knowledge about the kinetics and mechanism of the process. The present investigation is the first report of the thermal analysis of polypropylene hydroperoxide samples from two angles: (1) the thermal behavior of its decomposition and (2) whether such an analysis leads to knowledge of the concentration of hydroperoxide in the sample.

Item Type: Journal Article
Publication: Journa of Macromolecular Science, Part A
Publisher: Taylor and Francis Group
Additional Information: Copyright of this article belongs to Informa Plc.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 20 Nov 2009 10:36
Last Modified: 20 Nov 2009 10:36
URI: http://eprints.iisc.ac.in/id/eprint/20244

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