Aducts of Lanthanide Perchlorates with N,N,N',N'-Tetramethyl Oxydiacetamide

Premlatha, C and Soundararajan, S (1980) Aducts of Lanthanide Perchlorates with N,N,N',N'-Tetramethyl Oxydiacetamide. In: Journal of Inorganic and Nuclear Chemistry, 42 (12). pp. 1783-1786.

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Abstract

Lanthanide coordination complexes with unidentate and bidentate amide ligands have been widely reported in the literature[l].In contrast, however, coordination compounds with tridentate ligands and with ligands containing ether oxygen as donor atoms to lanthanides have received little attention. In this paper we report the preparation and characterization of complexes formed by the interaction of the lanthanide perchlorates with N, N, N', N'- tetramethyloxydiacetamide (TMODA). The new complexes have been characterized by analysis, conductance, IR and electronic spectra. In addition, ~H and '3C NMR spectra of the ligand and its diamagnetic La ~+ and y3+ complexes are also discussed.

Item Type:	Journal Article
Publication:	Journal of Inorganic and Nuclear Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	14 May 2009 06:56
Last Modified:	19 Sep 2010 05:31
URI:	http://eprints.iisc.ac.in/id/eprint/20049

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