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New main group ligands for complexation with transition and inner transition elements

Krishnamurthy, SS (1996) New main group ligands for complexation with transition and inner transition elements. In: Symposium on Modern Trends in Inorganic Chemistry, Aug 17-19, 1995, University Hyderabad, Hyderabad, India, pp. 111-121.

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Symmetrical and unsymmetrical diphosphinoamines of the type X(2)PN(R)PX(2) and X(2)PN(R)YY' offer vast scope for the synthesis of a variety of transition metal organometallic complexes. Diphosphinoamines can be converted into their dioxides which are also accessible from appropriate (chloro)phosphane oxide precursors. The diphosphazane dioxides form an interesting series of complexes with lanthanide and actinide elements. Structural and spectroscopic studies have been carried out on a wide range of transition metal complexes incorporating linear P-N-P ligands and judiciously functionalized cyclophosphazanes and cyclo-phosphazenes.

Item Type: Conference Paper
Publication: Proceedings of The Indian Academy of Sciences-Chemical Sciences
Publisher: Springer India, in co-publication with Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 07 Dec 2009 06:32
Last Modified: 19 Sep 2010 05:29
URI: http://eprints.iisc.ac.in/id/eprint/19614

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