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Enantiospecific total synthesis of (+)-2-pupukeanone

Srikrishna, A and Reddy, TJ (1997) Enantiospecific total synthesis of (+)-2-pupukeanone. In: Journal Of The Chemical Society-Perkin Transactions 1 (22). pp. 3293-3294.

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he first total synthesis of chiral 2-pupukeanone (+)-4, starting from R-carvone (-)-7 employing a 5-exo-trig radical cyclisation as the key reaction for the construction of the tricyclic isotwistane carbon framework, is described.

Item Type: Journal Article
Publication: Journal Of The Chemical Society-Perkin Transactions 1
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 03 Jun 2009 06:23
Last Modified: 19 Sep 2010 05:26
URI: http://eprints.iisc.ac.in/id/eprint/18939

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