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La0.9Sr0.1Ga0.8Mn0.2O2.85: a new oxide ion conductor

Thangadurai, V and Shukla, AK and Gopalakrishnan, J (1998) La0.9Sr0.1Ga0.8Mn0.2O2.85: a new oxide ion conductor. In: Chemical Communication, 23 . pp. 2647-2648.

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Isovalent substitution of Mn(II) for Mg(II) in the oxide ion conductor, La0.9Sr0.1Ga0.8Mg0.2O2.85, yields a new oxide ion conductor which exhibits an ionic conductivity (sigma = 4.6 x 10(-2) S cm(-1) at 800 degrees C) that is comparable to the conductivity of the Mg(II) analogue; interestingly, the Mn(Ir) oxide has a lower activation energy for conduction (E-a = 0.47 eV) than the Mg(II) oxide.

Item Type: Journal Article
Publication: Chemical Communication
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 31 Aug 2009 06:59
Last Modified: 19 Sep 2010 05:25
URI: http://eprints.iisc.ac.in/id/eprint/18850

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