Enantiodivergent synthesis of both antipodes of hydroxy-exo-brevicomin from L-(D)-tartaric acid

Prasad, Kavirayani R and Anbarasan, Pazhamalai (2006) Enantiodivergent synthesis of both antipodes of hydroxy-exo-brevicomin from L-(D)-tartaric acid. In: Tetrahedron, 62 (35). pp. 8303-8308.

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Abstract

An enantiodivergent approach to both antipodes of hydroxy-exo-brevicomin was achieved from a common chiral precursor L-(+)-tartaric acid. The strategy utilizes the elaboration of a keto-Weinreb amide and successive stereoselective reductions.

Item Type:	Journal Article
Publication:	Tetrahedron
Publisher:	Elsavier
Additional Information:	Copyright of this article belongs to Elsavier.
Keywords:	Stereoselective reduction; L-(+)-Tartaric acid;Hydroxy-exo-brevicomin;6,8-Dioxabicyclo[3.2.1]octane.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	23 Mar 2009 09:04
Last Modified:	19 Sep 2010 05:25
URI:	http://eprints.iisc.ac.in/id/eprint/18749

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